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The glycones pre- sent on cell membranes have been implicated in the conformation, stability, and sorting of proteins, in the attachment of microbes and toxins to cell surfaces, in cell-cell interactions, cell differentiation, 95, 248, 249 C-acylation 159 C-alkylation 153 O-alkylation 251 decarboxylation 159, 266 dianions 153, 158, 159, 179, 196 preparation 47, 173, 181, 184, 189 problematic 261 Carboxylic esters acidolysis 41 C-alkylation 148, 153156, 159, 169, 185, 187, 192, 193, 198, 324, 328 aminolysis 264 halogenation 84, 179 metalation 153156, 167169, 173, 185, 187, 192, 196, 198 preferred conformation 315 preparation 251254 transesterification 240, 266, 274, 275 Catalysis by enantiomerically pure complexes 4, 36, 111, 114 enantiomerically pure nucleophiles 337 enzymes 334336, 338, 339 palladium 111, 114, 235, 236, 245, 279301 Cesium carboxylates 251 Cesium hydroxide 232, 233, 344, 345 Cesium fluoride 229, 233, 251, 284 Chain reactions 45, 6062 Chain structure, in cyclizations 315 Chelate formation organolithium compounds 162170, 177181, 186, 194 organopalladium compounds 281, 300 Chiral auxiliaries 4, 36, 111, 114, 158, 168, 194, 198, 337 Chloroacetic acid, dianion 159 Chloroacetonitrile 87 Chlorobenzene, metalation 178 Chlorocyclohexane, conformation 20 Chloroform 83, 84 a-Chloro Grignard compounds 201 Chlorohydrins (2-chloroethanols) cyclization 59, 170, 171, 318 preparation 121124, 171 1-Chloro-6-iodohexane, metalation 191 Chloromethylation 24 Chloromethyl methyl ether 44, 79 39 20 Carbanions acyl 173175 alkylation 143182 allylic 38, 104, 150155, 167, 168, 171 amide-derived 155, 156 aromatic 175 benzylic 105, 151, 152, 180 bridgehead 157 configurational stability cyclization 190193 dimerization formyl 173 generation a-halogen 197 50, 176, 178, 179, 195, 196 201 b-halogen 143149 159, 170, 171, 183185, 189, 177180, 184, 185, 188 a-heteroatom 161 imidoyl 173175 with leaving groups in b position 184 a-nitrogen b-nitrogen oxidation a-oxygen b-oxygen propargylic 150155, 159, 160, 171 rearrangement 160, 161, 166, 193, 194 162165, 194, 200 178180, 186188 50, 157, 164, 167, 195, 292 165170, 184, 194, 200 184186, 190 stability a-sulfur b-sulfur tautomers of carbenes 183, 196 vinylic 171173, 183, 184, 189, 190, 199, 182 165170, 187, 198 187 201, 202 Carbazoles, N-alkylation Carbene complexes 294 Carbenes 183, 184, 196 Carbocations 238 formation 59, 60, 62, 320323 FriedelCrafts alkylation with 64, 69, 93, 313 rearrangement 69, 252, 320, 322 Carbohydrates, O-tritylation 59 Carbon monoxide, reaction with alcoholates 173 organolithium compounds organopalladium complexes 173, 174 291 Carbon tetrachloride 83, 84 Carbonylation, see Carbon monoxide 3-Chloroperbenzoic acid 2-Chlorotetrahydropyran Chlorovinyl carbanions Carboxylate dianions Carboxylic acids acidity 144, 146 158 172, 184, 188, 189, 4-Chromanones, deprotonation 186 202 Equivalence Groups 51 cells where they are expressed (Gómez-Skarmeta et al.

TableinformationfromMicrosoftWebsite,www. We dont know for certain that they had slept as spores, but we do know that when things begin to get too salty, these bacteria do rush toward becoming spores.

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